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Organic Chemistry

Working Paper

Iridium-Catalyzed Silylation of C-H bonds in Unactivated Arenes: A Sterically-Encumbered Phenanthroline Ligand Accelerates Catalysis Enabling New Reactivity

Caleb Karmel, Zhewei Chen, John Hartwig

Version 1 posted 21 February 2019

768

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Catalysis

Working Paper

Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand

Caleb Karmel, Camille Rubel, Elena Kharitonova, John Hartwig

Version 1 posted 28 October 2019

1,164

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Catalysis

Working Paper

Iridium-Catalyzed Regio- and Enantioselective Propargylic C−H Silylation

Jin Zhu, Hai Chang, Yiming Wang

Version 1 posted 09 June 2023

599

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Organometallic Chemistry

Working Paper

Persilylation of Ferrocene: The Ultimate Discipline in Sterically Overcrowded Metal Complexes

Susanne Margot Rupf, Robin Sievers, Paulin Sylvia Riemann, Marc Reimann, Martin Kaupp, Carlo Fasting, Moritz Malischewski

Version 1 posted 20 March 2023

169

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Organic Chemistry

Working Paper

Nickel-Catalyzed [4+1] Sila-Cycloaddition: A Divergent Synthesis of Silacarbocycles from Trichlorosilanes

Liangliang Qi, Peng-Fei Xu, Yu-Ke Wu, Xiaobo Pang, Xing-Zhong Shu

Version 1 posted 12 November 2024

439

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Catalysis

Working Paper

Harnessing Supported Gold Nanoparticle as a Single-Electron Transfer Catalyst for Decarboxylative Cross-Coupling

Hiroki Miura, Kaede Ameyama, Tetsuya Shishido

Version 1 posted 16 December 2022

321

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Catalysis

Working Paper

Diverse Alkyl–Silyl Cross-Coupling via Homolysis of Unactivated C(sp3)–O Bonds with the Cooperation of Gold and Amphoteric Oxides

Hiroki Miura, Masafumi Doi, Yuki Yasui, Yosuke Masaki, Hidenori Nishio, Tetsuya Shishido

Version 1 posted 05 September 2022

465

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Catalysis

Working Paper

Carboxylate catalysis: a mild catalytic O-silylative aldol reaction of aldehydes and ethyl diazoacetate

Saara Riuttamäki, Anton Bannykh, Anniina Kiesilä, Petri Pihko

Version 2 posted 20 February 2023

466

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Organic Chemistry

Working Paper

Site-Selective Electrochemical C–H Silylations of Pyridines Enabled by Temporary Reductive Dearomatization

Zhihao Yang, Xuan Liu, Tianyuan Zhang, Hirofumi Maekawa, Xin-Qi Hao, Mao-Ping Song

Version 1 posted 08 April 2024

750

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Organic Chemistry

Working Paper

Synthesis of heterocyclic analogues of Mosher's acid

Igor Pervak, Andrii Kyrylchuk, Aleksandr Yurchenko, Roman Rudenko, Pavlo Shynkarenko, Yevhenii Novodvorskyi, Evgenij Zarudnitskii

Version 1 posted 05 December 2024

158

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10 results in Silylation in Keywords: Silylation

Iridium-Catalyzed Silylation of C-H bonds in Unactivated Arenes: A Sterically-Encumbered Phenanthroline Ligand Accelerates Catalysis Enabling New Reactivity

Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand

Iridium-Catalyzed Regio- and Enantioselective Propargylic C−H Silylation

Persilylation of Ferrocene: The Ultimate Discipline in Sterically Overcrowded Metal Complexes

Nickel-Catalyzed [4+1] Sila-Cycloaddition: A Divergent Synthesis of Silacarbocycles from Trichlorosilanes

Harnessing Supported Gold Nanoparticle as a Single-Electron Transfer Catalyst for Decarboxylative Cross-Coupling

Diverse Alkyl–Silyl Cross-Coupling via Homolysis of Unactivated C(sp3)–O Bonds with the Cooperation of Gold and Amphoteric Oxides

Carboxylate catalysis: a mild catalytic O-silylative aldol reaction of aldehydes and ethyl diazoacetate

Site-Selective Electrochemical C–H Silylations of Pyridines Enabled by Temporary Reductive Dearomatization

Synthesis of heterocyclic analogues of Mosher's acid

10 results in Keywords: Silylation