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Organic Chemistry

Working Paper

Switching Between MHAT and Concerted Pathway: Ligand Controlled Regiodivergent Synthesis of Alkyl-Alkoxysilanes

Bincy Chindan, Anagha Syam, Thayalan Rajeshkumar, Laurent Maron, Ramesh Rasappan

Version 1 posted 06 December 2024

349

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Organometallic Chemistry

Working Paper

Molybdenum Carbonyl Assisted Reductive Tetramerization of CO by Activated Magnesium(I) Compounds: Squarate Dianion vs. Metallo-Ketene Formation

K Yuvaraj, Jeremy Mullins, Thayalan Rajeshkumar, Iskander Douair, Laurent Maron, Cameron Jones

Version 1 posted 22 March 2023

309

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Inorganic Chemistry

Working Paper

Steric Control of Mg‒Mg Bond Formation vs N2 Activation in the Potassium Reduction of Bulky Magnesium Diamide Complexes

Rahul Mondal, Matthew Evans, Dat Nguyen, Thayalan Rajeshkumar, Laurent Maron, Cameron Jones

Version 1 posted 23 November 2023

377

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Inorganic Chemistry

Working Paper

Oxidation-Induced Ambiphilicity Triggers N-N Bond Formation and Dinitrogen Release in Octahedral Terminal Molybdenum (V) Nitrido Complexes

C. Christopher Almquist, Thayalan Rajeshkumar, H. D. A. Chathumal Jayaweera, Nicole Removski, Wen Zhou, Benjamin Gelfand, Warren Piers, Laurent Maron

Version 1 posted 03 November 2023

613

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Inorganic Chemistry

Working Paper

Spontaneous Ammonia Oxidation Through Coordination Induced Bond Weakening in Molybdenum Complexes of a Dianionic Pentadentate Ligand Platform

C. Christopher Almquist, Nicole Removski, Thayalan Rajeshkumar, Benjamin Gelfand, Warren Piers, Laurent Maron

Version 1 posted 09 March 2022

705

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Inorganic Chemistry

Working Paper

Reductive Activation of N2 using a Calcium/Potassium Bimetallic System Supported by an Extremely Bulky Diamide Ligand

Rahul Mondal, Yuvaraj Kuppusamy, Thayalan Rajeshkumar, Laurent Maron, Cameron Jones

Version 1 posted 02 September 2022

889

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Inorganic Chemistry

Working Paper

Deciphering the role of anions and secondary coordination sphere in tuning anisotropy in Dy(III) air-stable D5h SIMs

Sandeep Gupta, Sourav Dey, Thayalan Rajeshkumar, Gopalan Rajaraman, Ramaswamy Murugavel

Version 1 posted 29 September 2021

365

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Inorganic Chemistry

Working Paper

Coordination and Activation of N2 at Low-Valent Magnesium using a Cooperative Heterobimetallic Approach: Synthesis and Reactivity of a Masked Dimagnesium Diradical

Rahul Mondal, Matthew J Evans, Thayalan Rajeshkumar, Laurent Maron, Cameron Jones

Version 1 posted 15 May 2023

897

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Inorganic Chemistry

Working Paper

Stabilization and One Electron Reduction of a Silicon Analogue of a Carboxylic Acid Anhydride

Yixiao Jiang, K Yuvaraj, Thayalan Rajeshkumar, Li Feng Lim, Nicholas Cox, Laurent Maron, Cameron Jones

Version 1 posted 30 November 2023

271

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Inorganic Chemistry

Working Paper

The photo-isomerization of the cyclononatetraenyl ligand and related rare earth complexes

Lucie Pedussaut, Nolwenn Mahieu, Camille Chartier, Thayalan Rajeshkumar, Maxime Tricoire, Iskander Douair, Nicolas Casaretto, Laurent Maron, Gregory Danoun, Gregory Nocton

Version 2 posted 19 July 2024

200

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Refine Search

11 results in Thayalan Rajeshkumar in Authors: Thayalan Rajeshkumar

Switching Between MHAT and Concerted Pathway: Ligand Controlled Regiodivergent Synthesis of Alkyl-Alkoxysilanes

Molybdenum Carbonyl Assisted Reductive Tetramerization of CO by Activated Magnesium(I) Compounds: Squarate Dianion vs. Metallo-Ketene Formation

Steric Control of Mg‒Mg Bond Formation vs N2 Activation in the Potassium Reduction of Bulky Magnesium Diamide Complexes

Oxidation-Induced Ambiphilicity Triggers N-N Bond Formation and Dinitrogen Release in Octahedral Terminal Molybdenum (V) Nitrido Complexes

Spontaneous Ammonia Oxidation Through Coordination Induced Bond Weakening in Molybdenum Complexes of a Dianionic Pentadentate Ligand Platform

Reductive Activation of N2 using a Calcium/Potassium Bimetallic System Supported by an Extremely Bulky Diamide Ligand

Deciphering the role of anions and secondary coordination sphere in tuning anisotropy in Dy(III) air-stable D5h SIMs

Coordination and Activation of N2 at Low-Valent Magnesium using a Cooperative Heterobimetallic Approach: Synthesis and Reactivity of a Masked Dimagnesium Diradical

Stabilization and One Electron Reduction of a Silicon Analogue of a Carboxylic Acid Anhydride

The photo-isomerization of the cyclononatetraenyl ligand and related rare earth complexes

11 results in Authors: Thayalan Rajeshkumar