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Site-selective Protonation of the One-electron Reduced Cofactor in [FeFe]-Hydrogenase

Konstantin Laun, Iuliia Baranova, Jifu Duan, Leonie Kertess, Florian Wittkamp, Ulf-Peter Apfel, Thomas Happe, Moritz Senger, Sven T. Stripp

Version 3 posted 16 September 2020

1,140

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1

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Organometallic Chemistry

Working Paper

CO Reductive Oligomerization by a Divalent Thulium Complex and CO2-Induced Functionalization

Thomas Simler, Karl N. McCabe, Laurent Maron, Gregory Nocton

Version 1 posted 29 October 2021

332

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Catalysis

Working Paper

Linear Free Energy Relationships and Transition State Analysis of CO2 Reduction Catalysts Bearing Second Coordination Spheres with Tunable Acidity

Kaeden Teindl, Brian Patrick, Eva Nichols

Version 1 posted 19 April 2023

329

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Catalysis

Working Paper

Photoinduced transfer hydrogenation of nitrogen to ammonia using a Mo-catalyst and a Hantzsch ester donor is demonstrated with and without an Ir-photoredox co-catalyst

Christian Johansen, Emily Boyd, Jonas Peters

Version 1 posted 13 June 2022

815

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1

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Biological and Medicinal Chemistry

Working Paper

Supramolecular Activation of S8 by Cucurbiturils in Water and Mechanism of Reduction to H2S by Thiols: Insights into Biological Sulfane Sulfur Trafficking

Arman Garcia, Lev Zakharov, Michael Pluth

Version 1 posted 27 May 2022

380

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Inorganic Chemistry

Working Paper

Reversible O–H bond activation by tripodal tris(nitroxide) aluminum and gallium complexes

Joseph S. Scott, Mika L. Maenaga, Audra J. Woodside, Vivian W. Guo, Alex R. Cheriel, Michael R. Gau, Paul R. Rablen, Christopher R. Graves

Version 2 posted 22 September 2023

303

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Catalysis

Working Paper

Catalytic reduction of dinitrogen to silylamines by earth-abundant lanthanide and group 4 complexes

Anthony Wong, Matthew Hernandez, Jaden Lara, Francis Lam, Michael Trinh, Rory Kelly, Tatsumi Ochiai, Guodong Rao, David Britt, Nikolas Kaltsoyannis, Polly Arnold

Version 2 posted 23 November 2023

1,091

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Organometallic Chemistry

Working Paper

Alternating substrate/ligand-metal coordination enables a low-energy pathway for C-O bond cleavage in the electrocatalytic reduction of carbon dioxide

Hemlata Agarwala, Xiaoyu Chen, Julien R. Lyonnet, Ben A Johnson, Mårten Ahlquist, Sascha Ott

Version 2 posted 21 May 2021

767

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Inorganic Chemistry

Working Paper

Room Temperature Alkali Metal Reduction of Carbon Dioxide

Lucas A. Freeman, Akachukwu D. Obi, Haleigh R. Machost, Andrew Molino, Asa W. Nichols, Diane A. Dickie, David J. D. Wilson, Charles Machan, Robert Gilliard

Version 2 posted 05 August 2020

1,215

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Inorganic Chemistry

Working Paper

Modulating the Frontier Orbitals of an Aluminylene for Facile Dearomatization of Inert Arenes

Xin Zhang, Liu Leo Liu

Version 2 posted 29 December 2021

692

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17 results in Small molecule activation in Keywords: Small molecule activation

Site-selective Protonation of the One-electron Reduced Cofactor in [FeFe]-Hydrogenase

CO Reductive Oligomerization by a Divalent Thulium Complex and CO2-Induced Functionalization

Linear Free Energy Relationships and Transition State Analysis of CO2 Reduction Catalysts Bearing Second Coordination Spheres with Tunable Acidity

Photoinduced transfer hydrogenation of nitrogen to ammonia using a Mo-catalyst and a Hantzsch ester donor is demonstrated with and without an Ir-photoredox co-catalyst

Supramolecular Activation of S8 by Cucurbiturils in Water and Mechanism of Reduction to H2S by Thiols: Insights into Biological Sulfane Sulfur Trafficking

Reversible O–H bond activation by tripodal tris(nitroxide) aluminum and gallium complexes

Catalytic reduction of dinitrogen to silylamines by earth-abundant lanthanide and group 4 complexes

Alternating substrate/ligand-metal coordination enables a low-energy pathway for C-O bond cleavage in the electrocatalytic reduction of carbon dioxide

Room Temperature Alkali Metal Reduction of Carbon Dioxide

Modulating the Frontier Orbitals of an Aluminylene for Facile Dearomatization of Inert Arenes

17 results in Keywords: Small molecule activation