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Organometallic Chemistry

Working Paper

Oxidation-Induced Ligand Swap: Oxygen Insertion into a Cobalt-Phosphine Complex

Sriram Katipamula, Thomas Emge, Kate Waldie

Version 1 posted 06 June 2024

206

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1

Citations

Organometallic Chemistry

Working Paper

Bis(N-xylyl-imino)phenyl “NCN” Iridium Pincer Complexes. Thermodynamics of Ligand Binding and C-C Bond Cleavage

Soumyadipa Das, Souvik Mandal, Santanu Malakar, Thomas J. Emge, Alan S. Goldman

Version 1 posted 02 November 2023

237

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Catalysis

Working Paper

Using Host-Guest Chemistry to Examine the Effects of Porosity and Catalyst-Support Interactions on CO2 Reduction

Daniel A. Rothschild, Zeyu Cao, Feng Xie, Belvin Thomas, Thomas J. Emge, Jing Li, Tewodros Asefa, Mark C. Lipke

Version 1 posted 18 December 2024

85

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Catalysis

Working Paper

Metal-Ligand Tautomerism, Electron-Transfer, and C(sp3)-H Activation by a 4 Pyridinyl-Pincer Iridium Hydride Complex

Tariq Bhatti, Akshai Kumar, Ashish Parihar, Thomas Emge, Faraj Hasanayn, Alan Goldman

Version 2 posted 29 March 2023

533

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Catalysis

Working Paper

Regioselective Gas-Phase n-Butane Transfer Dehydrogenation via Silica-Supported Pincer-Iridium Complexes

Boris Sheludko, Cristina Castro, Chaitanya Khalap, Thomas Emge, Alan Goldman, Fuat E. Celik

Version 1 posted 28 August 2020

331

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Organometallic Chemistry

Working Paper

Two-Electron Redox Tuning of Cyclopentadienyl Cobalt Complexes Enabled by the Phenylenediamide Ligand

Minzhu Zou, Thomas J. Emge, Kate M. Waldie

Version 1 posted 01 March 2023

523

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1

Citations

Catalysis

Working Paper

Reactivity of Iridium Complexes of a Triphosphorus-Pincer Ligand Based on a Secondary Phosphine. Catalytic Alkane Dehydrogenation and the Origin of Extremely High Activity

Benjamin Gordon, Nicholas Lease, Thomas Emge, Faraj Hasanayn, Alan Goldman

Version 1 posted 14 December 2021

476

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2

Citations

Inorganic Chemistry

Working Paper

Controlling intramolecular and intermolecular electronic coupling of radical ligands in a series of cobaltoviologen complexes

Brice J. O. Kessler, Iram F. Mansoor, Derek I. Wozniak, Thomas J. Emge, Mark C. Lipke

Version 1 posted 11 April 2023

274

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Organometallic Chemistry

Working Paper

Pincer-ligated Iridium Complexes with Low-Field Ancillary Ligands: Complexes of (iPrPCP)IrCl2 and Comparison with (iPrPCP)IrHCl

Ashish Parihar, Thomas J. Emge, Alan S. Goldman

Version 1 posted 20 December 2023

275

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1

Citations

Catalysis

Working Paper

Alkane Dehydrogenation and H/D Exchange by a Cationic Pincer-Ir(III) Hydride: A Novel Mechanism of C-H Addition and 𝛽-H Elimination Leads to Unprecedented Selectivity

Ashish Parihar, Thomas J. Emge, Faraj Hasanayn, Alan S. Goldman

Version 1 posted 29 October 2024

316

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13 results in Thomas Emge in Authors: Thomas Emge

Oxidation-Induced Ligand Swap: Oxygen Insertion into a Cobalt-Phosphine Complex

Bis(N-xylyl-imino)phenyl “NCN” Iridium Pincer Complexes. Thermodynamics of Ligand Binding and C-C Bond Cleavage

Using Host-Guest Chemistry to Examine the Effects of Porosity and Catalyst-Support Interactions on CO2 Reduction

Metal-Ligand Tautomerism, Electron-Transfer, and C(sp3)-H Activation by a 4 Pyridinyl-Pincer Iridium Hydride Complex

Regioselective Gas-Phase n-Butane Transfer Dehydrogenation via Silica-Supported Pincer-Iridium Complexes

Two-Electron Redox Tuning of Cyclopentadienyl Cobalt Complexes Enabled by the Phenylenediamide Ligand

Reactivity of Iridium Complexes of a Triphosphorus-Pincer Ligand Based on a Secondary Phosphine. Catalytic Alkane Dehydrogenation and the Origin of Extremely High Activity

Controlling intramolecular and intermolecular electronic coupling of radical ligands in a series of cobaltoviologen complexes

Pincer-ligated Iridium Complexes with Low-Field Ancillary Ligands: Complexes of (iPrPCP)IrCl2 and Comparison with (iPrPCP)IrHCl

Alkane Dehydrogenation and H/D Exchange by a Cationic Pincer-Ir(III) Hydride: A Novel Mechanism of C-H Addition and 𝛽-H Elimination Leads to Unprecedented Selectivity

13 results in Authors: Thomas Emge