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Abstract
Poly(ethylenedioxythiophene) (PEDOT) bearing oligosiloxane moiety at the side chain was synthesized by oxidative polymerization. The formation of the thin film was also carried out with FeIII oxidant on the substrate. Alternatively, the thin-film formation was performed by electrolytic polymerization on the electrode. The obtained thin films exhibited electric conductivities up to 101 Scm–1 and thermal stabilities up to 300 °C.
Introduction.
Supplementary materials
Title
Supporting Information
Description
Table of contents
Experimental details S2
Results on TG-DTA analyses (Table S1) S9
Model studies on the reactivity of disiloxane
under oxidative polymerization (Figure S1) S9
Relationship of the electric conductivity
with the amount of oxidant (Table S2) S11
Electrolytic polymerization apparatus (Figure S2) S12
Table on the relationship of the electric conductivity of PEDOT film
with the reaction period in the electrolytic polymerization S12
Copies of NMR spectra S13
References S25
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