Exploring the Synthesis of a Rare-Earth Cluster-Based Metal–Organic Framework Using Alternative Yttrium(III) Precursors

10 April 2025, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The synthesis of rare-earth cluster-based MOFs is often performed using metal nitrate salts as precursors. In this work, we demonstrate that six other Y(III) precursors can be used as alternatives in the synthesis of Y-CU-45 (CU = Concordia University), yielding reproducible results and high-quality materials.

Keywords

MOFs
RE-MOFs
lanthanoids
lanthanides
yttrium
MOF-808
RE-CU-45

Supplementary materials

Title
Description
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Supporting Information
Description
Experimental procedures, PXRD, Nitrogen Gas Adsorption, SEM, TGA, Table of pKas
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