Mitigation of Indoor Ozone and Secondary Products from 222 nm Germicidal UV Using Commercial Air Cleaners

31 March 2025, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Far-UVC light, especially germicidal UV light at 222 nm (GUV222), has received considerable attention for its potential to deactivate airborne pathogens indoors and prevent the spread of infectious disease. However, GUV222 also generates ozone (O3), posing human health risks and initiating additional photochemistry that may degrade indoor air quality. Air cleaners pose an opportunity to counteract the drawbacks of GUV222 by removing harmful byproducts; however, this has never been demonstrated. Here, we conduct laboratory experiments in a 7.5 m3 Teflon chamber using two commercially available air cleaners—a manganese-oxide-catalyst “ozone cleaner” and an activated-carbon-HEPA “volatile organic compound (VOC) + particulate matter (PM) cleaner”—in tandem with a GUV222 lamp. We show that both cleaner types remove a wide range of chemical species, including many not specifically targeted by the cleaners. Application of chamber results to a photochemical model environment suggests that a single cleaner can achieve modest reductions in O3 levels and substantial reductions in secondary pollutant levels within typical indoor environments. These results indicate that indoor air pollutants from GUV222 can be mitigated through the use of air cleaning technology, thereby improving indoor air quality while maximizing the potential benefit of germicidal UV for human health.

Keywords

ultraviolet germicidal irradiation
indoor air quality
air cleaners
ozone
photochemistry
volatile organic compounds
secondary organic aerosol
indoor pollutants

Supplementary materials

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Description
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Supporting Information
Description
Experimental methods and procedures; additional results and discussion (including CADR and fluence rate calculations; air cleaner emissions; time series of precursors and oxidation products; and SMPS data); model details and results (including additional model output figures and calculation of effective air changes per hour)
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