![Author ORCID: We display the ORCID iD icon alongside authors names on our website to acknowledge that the ORCiD has been authenticated when entered by the user. To view the users ORCiD record click the icon. [opens in a new tab]](https://chemrxiv.org/engage/assets/public/chemrxiv/images/logos/orcid.png)
Abstract
This paper reports the successful conversion of 1-arylallyloxysilanes into highly nucleophilic siloxyallylpotassium intermediates using (trimethylsilyl)methylpotassium as the base. These organopotassium species react regioselectively with various electrophiles, leading to the formation of the corresponding 3-functionalized (Z)-silyl enol ethers. The resulting silyl enol ethers can undergo a range of α-functionalization reactions, yielding ketones with diverse structures. Thus, our method enables the effective utilization of 1-arylallyloxysilanes as formal precursors to potassium homoenolate equivalents of ketones.
Supplementary materials
Title
Supporting Information
Description
General information, experimental procedures, computational study, characterization data, and NMR spectra.
Actions
