Abstract
Preparation of a 2-acetamido derivative of the rare 5,5-gem-dimethyl-deoxy carbohydrate noviose is reported in this study. The synthesis starts from readily available N-acetyl-ᴅ- mannosamine and tackles the introduction of the gem-dimethyl structural feature via a cyclopropanation and hydrogenolytic cleavage strategy, which can enable the synthesis of 2- amino noviose derivatives of both, L- and D-noviose.
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Title
Dataset for "Synthesis of 2-Acetylnoviosamine by Hydrogenolytic Cleavage of a Spirocyclopropane"
Description
This dataset contains as a ZIP file:
Characterisation data (such as e.g. NMR, IR, MS spectra)
NMR raw data
Crystallographic data
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