Role of Surface Oxygen in α-MoC Catalyst Stability and Activity Under Electrooxidation Conditions

Transition metal carbides are attractive, low-cost alternatives to Pt group metals, exhibiting multifunctional acidic, basic, and metallic sites for catalysis. Their widespread applications are often hindered by a high surface affinity for oxygen, which blocks catalytic sites. However, recent reports indicate that the α-MoC phase is a stable and effective co-catalyst for reactions in oxidative or aqueous environments. In this work, we elucidate the factors affecting the stability and catalytic activity of α-MoC under mild electrooxidation conditions (0–0.8 V SHE) using density functional theory calculations, kinetics-informed surface Pourbaix diagram analysis, electronic structure analysis, and cyclic voltammetry. Both computational and experimental data indicate that α-MoC is significantly more resistant to electrooxidation by H2O than β-Mo2C. This higher stability is attributed to structural and kinetic factors, as the Mo-terminated α-MoC surface disfavors substitutional oxidation of partially exposed, less oxophilic C* atoms by hindering CO/CO2 removal. The surface exposes H2O-protected [MoC2O2] and [MoC(CO)O2] oxycarbidic motifs available for catalysis in a wide potential window. At higher potentials, they convert to unstable [Mo(CO)2O2], resulting in material degradation. Using formic acid as a probe molecule, we obtain evidence for Pt-like O*-mediated O-H and C-H bond activation pathways. The kinetic barrier for the rate-limiting C-H bond activation correlates with the hydrogen affinity of the site in the order O*/Mofcc > O*/Ctop > O*/Motop. To mitigate the site-blocking effect of surface-bound H2O and bidentate formate, doping with Pt was investigated to make the surface less oxophilic and more carbophilic, indicating a possible design strategy toward more active and selective carbide electrocatalysts.