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Tuning the electronic properties of Zr UiO-66 through defect-functionalised multivariate modulation.

28 May 2024, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The multivariate modulation of Metal-Organic Frameworks is presented as a valuable tool to introduce multiple functional units into UiO-66 while increasing its porosity. This manuscript encloses a comprehensive study using p-functionalised benzoate -NO2, -SO3 and -SH modulators, rationalizing the defects introduced and their impact on properties.

Keywords

Metal-Organic Frameworks
Porous materials
Defects
Multivariate modulation
multifunctionalisation
Pair distribution function
electronic properties

Supplementary materials

Title
Description
Actions
Title
Electronic Supplementary Information
Description
Details of synthesis, characterisation, and properties of materials
Actions

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Version History

May 28, 2024 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-zb5t4
D O I: 10.26434/chemrxiv-2024-zb5t4 [opens in a new tab]

Funding

‘‘la Caixa” Foundation
LCF/BQ/PR23/11980041

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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