Pd-Catalyzed Transfer Hydrogenation of Alkenes Using Tetrahydroxydiboron as the Sole Hydrogen Donor

Tetrahydroxydiboron-mediated catalytic transfer hydrogenations have typically involved co-additives that, like tetrahydroxydiboron itself, are also H atom donors. Herein, we report an alkene transfer hydrogenation using tetrahydroxydiboron as the sole source of H atoms. The reaction uses Pd(OAc)2 as a convenient and economical pre-catalyst, and cyclic monoethers are competent solvents. Highly efficient alkene deuteration is demonstrated using tetradeuteroxydiboron.