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Abstract
A porous three-component hydrogen bonded framework, 1∙biphen∙TP, was prepared from a tetra-amidinium component (14+) and two different dianions, benzene-1,4-dicarboxylate (terephthalate, TP2–) and biphenyl-4,4′-dicarboxylate (biphen2–). Interestingly, when the framework was prepared in ethanol/water, 1∙biphen∙TP forms even when an excess of either dicarboxylate is present. However, when only water is used as solvent, only two-component frameworks are formed.
Supplementary materials
Title
Supporting Information
Description
Synthesis and characterisation data, details of crystallisations, X-ray crystallography and water sorption experiments.
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