Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

T-Shaped Nickel Metalloradical Bearing a Phenalenyl-Based Tridentate Ligand

03 May 2024, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A T-shaped nickel(I) complex 1 bearing a phenalenyl-based tridentate ligand was synthesized. The electronic and spin struc-tures of 1 were elucidated through electronic absorption spectra, ESR, and XAFS measurements. Additionally, the metallo-radical reactivity of 1 toward diphenyl disulfide and alkyl halides was also demonstrated.

Keywords

metalloradical
nickel(I) complex
XAFS
phenalenyl

Supplementary materials

Title
Description
Actions
Title
Supporting Information
Description
Detailed experimental procedures, characterization of new com-pounds, and computational details.
Actions
Title
CIF
Description
CIF for Complex 4
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Version History

May 03, 2024 Version 1

Metrics

497
303
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-39t04
D O I: 10.26434/chemrxiv-2024-39t04 [opens in a new tab]

Funding

Japan Society for the Promotion of Science
JP23K13729, JP24H01852, JP24H02217, JP24H02206, JP24H02207
Shorai Foundation for Science and Technology

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

Share