Chemical Micromotors Move Faster at Oil-Water Interfaces

15 December 2023, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Many real-world scenarios involve interfaces, particularly liquid-liquid interfaces, that can fundamentally al-ter the dynamics of colloids. This is poorly understood for chemically active colloids that release chemicals into their environment. We report here the surprising discovery that micromotors—colloids that convert chemical fuels into self-propulsion—move significantly faster at an oil-water interface than on a glass substrate. Typical speed increases ranged from 3-6 times up to an order of magnitude, and were observed for different types of chemical motors or oils. Such speed increases are likely caused by faster chemical reactions at an oil-water interface than a glass-water interface, but the exact mechanism remains unknown. Our results provide valuable insights into the complex interactions between chemical micromotors and their environments, which are important for applications in the human body or in the removal of organic pollutants from water. In addi-tion, this study also suggests that chemical reactions occur faster at an oil-water interface, and that micromo-tors can serve as a probe for such an effect.

Keywords

Oil-water interface
Micromotor
Speed increase
Faster chemical reaction
Tilt angle

Supplementary materials

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