Model-Independent Statistical Averages of the Hydrodynamic Radius via Dynamic Light Scattering

06 November 2023, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

I present new, robust, and measurable nonparametric statistical averages that summarize major features of the distribution of the hydrodynamic radius. I explain how these descriptive statistical averages—the mean, standard deviation, and skewness of the intensity-weighted distribution—are obtained. Next, I demonstrate that—unlike the well-known and widely used Z-average and polydispersity index—these statistical averages bear a direct and physically meaningful interpretability. At the same time, these statistical averages are straightforward to obtain from experimental correlograms, and therefore, they merit a place in characterizing particle systems via DLS.

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