Direct environmental lead detection by photoluminescent perovskite formation with nanogram sensitivity

31 October 2023, Version 2
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Although the global ban of leaded gasoline has markedly reduced lead poisoning, many other environmental sources of lead exposure such as paint, pipes, mines, and recycling sites remain. Existing methods to identify these sources are either costly or unreliable. We here report a new sensitive and inexpensive lead detection method that relies on the formation of a perovskite semiconductor. The method only requires spraying the material of interest with methyl ammonium bromide and observing whether photoluminesence occurs under UV light to indicate the presence of lead. The method detects as little as 1.0 ng/mm² of lead by naked eye and 50 pg/mm² using a digital photo camera. We exposed more than 50 different materials to our reagent and found no false negatives or false positives. The method readily detects lead in soil, paint, glazing, cables, glass, plastics, and dust and could be widely used for testing the environment and preventing lead poisoning.

Keywords

Lead detection
Lead pollution
Perovskite
Photoluminescence
Lead paint
Lead glazing
paint
Large area screening

Supplementary materials

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Supplementary Information
Description
Supplementary information containing: 1. Photoluminescence measurement setup 2. List of tested materials and testing methods 3. Solvent screening 4. Different types of halide and halide mixtures 5. Comparison with commercial tests 6. XRF testing 7. Analysis in luminescence variation
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Test on crystal glass containing lead
Description
A real time application on crystal glass containing lead
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Test on pottery containing lead
Description
A real time test on pottery containing lead
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Test on a power cable containing lead
Description
Real time test on a power cable with a housing that contains lead
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