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Abstract
Photocleavable protecting groups (PPGs) enable light-dependent, spatiotemporal control over the release of a payload of interest. Here we describe the combination of two photochemical strategies for PPG optimization in one molecule, resulting in significant improvements in PPG photochemistry. Furthermore, we identify photo-isomerization as an important factor affecting PPG efficiency.
Supplementary materials
Title
Supporting Information
Description
Synthetic methods, Photochemical evaluation methods, and Computational Chemistry data
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