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ArI(NTf)2: The boundary of oxidative capacity for ArIL2?

14 September 2023, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Crystallographic characterization of NO2-C6H4-I(NTf)2 (NTF = bistriflimide) is reported. Experimental results find that this compound can perform oxidation reactions that ArI(OTf)2 is unable to and theoretical analysis indicates Ar-I(NTf)2 is the most oxidizing in the ArIL2 class of compound known and may also be the most oxidizing compound in the class practically possible.

Keywords

Iodine
Oxidizing Agents

Supplementary materials

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Version History

Sep 14, 2023 Version 1

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The content is available under CC BY NC 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-slnrf
D O I: 10.26434/chemrxiv-2023-slnrf [opens in a new tab]

Funding

Australian Research Council
DP200100013

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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