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Abstract
The redox reaction between a bulky BODIPY and a magnesium(I) reducing agent leads to the formal one-electron reduction of the BODIPY, initially generating a dipyrromethene-centred radical compound that dimerises via C–C bond formation. In contrast, reduction with magnesium anthracene leads to the formal two-electron reduction of the BODIPY, resulting in the formation of the corresponding anion.
Supplementary materials
Title
Supplementary Information
Description
Synthetic and characterising data for new compounds, NMR spectra of new compounds, X-ray crystallographic studies, EPR materials and methods.
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