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Air-stable methyldisulfide-functionalized metal bis(terpyridine) complexes

16 March 2023, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Metal bis(terpyidine) complexes comprising directly connected methyldisulfide groups are synthetically accessible and air-stable in solution for ≥7 d, in stark contrast to their thiol analogues. These compounds exhibit a rich solution electrochemistry, and provide a robust foundation for future studies of this prominent class of molecules adsorbed on metal surfaces.

Keywords

metal bis(terpyridine) complexes
self-assembled monolayers

Supplementary materials

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Description
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Title
Supporting information for: "Air-stable methyldisulfide-functionalized metal bis(terpyridine) complexes"
Description
Additional experimental details, synthetic, crystallographic, and electrochemical data, 1H and 13C{1H} NMR spectra for all new compounds.
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Now Published

Methyldisulfide groups enable the direct connection of air-stable metal bis(terpyridine) complexes to gold surfaces [opens in a new tab]
Christina D. M. Trang, Thomas Saal, Michael S. Inkpen journal article
Dalton Transactions , Volume 52, Issue 23
Online publication date: 2023

Version History

Mar 16, 2023 Version 2

Version Notes

The manuscript was revised to focus on the synthetic and solution electrochemical aspects of this work.

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2022-lrqzq-v2
D O I: 10.26434/chemrxiv-2022-lrqzq-v2 [opens in a new tab]

Funding

American Chemical Society Petroleum Research Fund
62751-DNI5
University of Southern California
National Science Foundation
DBI-0821671, CHE-0840366, CHE-1048807, CHE-2018740
National Institutes of Health
S10 RR25432

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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