Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

Heterogeneously Catalyzed Decarbonylation of Thioesters by Supported Nanoparticle Catalysts

16 February 2023, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

This study demonstrated a heterogeneously catalyzed system for decarbonylation of various aryl thioesters to produce thioethers and CO by utilizing CeO2- or hydroxyapatite-supported Ni or Pd nanoparticle catalysts. The Ni catalysts showed high catalytic activity, while the Pd catalysts possessed excellent functional group tolerance.

Keywords

decarbonylation
nanoparticles
nickel
palladium
thioesters

Supplementary materials

Title
Description
Actions
Title
Supporting Information for Heterogeneously Catalyzed Decarbonylation of Thioesters by Supported Nanoparticle Catalysts
Description
This supporting information contains experimental methods, spectral data, additional figures, additional tables, additional schemes, additional references, and NMR spectra.
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Now Published

Heterogeneously catalyzed decarbonylation of thioesters by supported Ni, Pd, or Rh nanoparticle catalysts [opens in a new tab]
Takehiro Matsuyama, Takafumi Yatabe, Kazuya Yamaguchi journal article
Organic & Biomolecular Chemistry , Volume 22, Issue 3
Online publication date: 2024

Version History

Feb 16, 2023 Version 1

Metrics

531
283
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-jn276
D O I: 10.26434/chemrxiv-2023-jn276 [opens in a new tab]

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

Share