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Synthesis, Structure, and Reactivity of a Gallylene Derivative Bearing a Phenalenyl-Based Ligand

01 February 2023, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Phenalenyl-based N,N-bidentate ligand-stabilized monovalent gallium(I) 1 was synthesized and characterized. Compound 1 promotes the oxidative addition of I-I, Si-Cl, C-I, and S-S bonds and oxidative cyclization with various Pi-components. Compound 1 can also coordinate to a tungsten complex to form a gallium-tungsten bond.

Keywords

Gallylene
Main Group Chemistry
Phenalenyl
Oxidative Addition
Oxidative Cyclization

Supplementary materials

Title
Description
Actions
Title
Supplementary Information
Description
Electronic Supplementary Information
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Title
CIF
Description
CCDC 2238068–2238073
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Version History

Feb 01, 2023 Version 2

Version Notes

Contents of Graphical Abstract was modified.

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License

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-jkhx3-v2
D O I: 10.26434/chemrxiv-2023-jkhx3-v2 [opens in a new tab]

Funding

Japan Society for the Promotion of Science
JP19K15564
Shorai Foundation for Science and Technology

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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