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Hybrid Catalysts for Enantioselective Photo-Phosphoric Acid Catalysis

23 January 2023, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The syntheses of two novel, organic and chiral photocatalysts are presented. By combining donoracceptor cyanoarene-based photocatalysts with a chiral phosphoric acid, bifunctional catalysts have been designed. In preliminary proof of concept reactions, their use in both enantioselective energytransfer and photoredox catalysis was demonstrated.

Keywords

photocatalysis
Phosphoric Acid Catalysis

Supplementary materials

Title
Description
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Title
Supporting Information for Hybrid Catalysts for Enantioselective Photo-Phosphoric Acid Catalysis
Description
Table of Content S1 Experimental Procedure S1.1 General Information S1.2 UV-VIS and Emission Spectra S1.3 Overview of Synthesis S1.3.1 Synthesis of PCI S1.3.1 Synthesis of PCII S1.4 Synthesis of Literature Reported Compounds S1.5 Synthesis of Novel Compounds S1.6 Proof-of-Principle Photoreactions S2 NMR-Data S3 References
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Version History

Jan 23, 2023 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-0v38p
D O I: 10.26434/chemrxiv-2023-0v38p [opens in a new tab]

Funding

National Institutes of Health
R35 GM118190
National Institutes of Health
S10OD024998
Deutsche Forschungsgemeinschaft
TRR 325 – 444632635
Studienstiftung des Deutschen Volkes
AR
Fonds der Chemischen Industrie
AR

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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