Comment on ”Crystallographic and theoretical study of
the atypical distorted octahedral geometry of the metal
chromophore of zinc(II) bis((1R,2R)-1,2-diaminocyclohexane) dinitrate”

Martin Lutz

doi:10.26434/chemrxiv-2023-psvdz

Organometallic Chemistry

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Comment on ”Crystallographic and theoretical study of the atypical distorted octahedral geometry of the metal chromophore of zinc(II) bis((1R,2R)-1,2-diaminocyclohexane) dinitrate”

04 January 2023, Version 1

Working Paper

Martin Lutz

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This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We comment on the crystal structure of an enanantipure chiral zinc complex which has been described by Ivanova & Spiteller (2022) erroneously in a centrosymmetric space group with the metal on an inversion center. Subsequent information about thermal motion, octahedral distortion and charge density in their article is highly flawed.

Keywords

symmetry

chirality

crystal structure validation

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symmetry

Version History

Jan 04, 2023 Version 1

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The content is available under CC BY NC ND 4.0

DOI

10.26434/chemrxiv-2023-psvdz

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content