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Abstract
We herein report a concise total synthesis of (±)-stepharine and (±)-pronuciferine using readily available reagents as the starting materials. This synthesis features a three-component Catellani reaction/Au-catalyzed 6-exo-dig cyclization for the assembly of 1-methylene-THIQ scaffold and an oxidative dearomatization for constructing spiro-cyclohexadienone scaffold.
Supplementary materials
Title
Supporting Information for A Concise Total Synthesis of (±)-Stepharine and (±)-Pronuciferine
Description
Supporting Information for
A Concise Total Synthesis of (±)-Stepharine and (±)-Pronuciferine
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