Translating Aqueous CO2 Hydrogenation Activity to Electrocatalytic Reduction with a Homogeneous Cobalt Catalyst

06 October 2022, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A molecular cobalt CO2 hydrogenation catalyst was explored for electrocatalytic CO2 reduction under aqueous conditions. The resulting pH-dependent selectivity between H2 and HCO2- is rationalized through thermodynamic analysis and stoichiometric experiments.

Keywords

Electrocatalysis
CO2 Reduction
Homogeneous
Aqueous

Supplementary materials

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Description
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Supplementary Information
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Experimental methods, NMR spectra, electrochemical data, electronic absorption data
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