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Abstract
Examples of unsymmetric diphosphines, especially those with customized secondary coordination spheres, are rare. Herein, we provide an approach towards a Lewis acid-containing analogue of the bulky diphosphine, 1,2-bis(di-tert-butylphosphino)ethane that contains a single boron moiety. The coordination chemistry of this ligand and its allyl precursor have been explored using nickel(0).
Supplementary materials
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CIF File
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Crystal File
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XYZ Coordinate File
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XYZ Coordinate File
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Electronic Supporting Information
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1H, 13C{1H}, 31P{1H}, and 11B{1H} NMR spectra for all complexes. Experimental, X-ray, and Computational Methods.
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