Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines

20 October 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report the use of a cyclic carbodiphosphorane catalyst for ketone and imine hydroboration reactions. To our knowledge, this represents the first use of a carbodiphosphorane as an organocatalyst. The carbodiphospohorane shows superior catalytic activity compared to other neutral carbon nucleophiles tested.

Keywords

Lewis base catalysis
hydroboration
main group chemistry

Supplementary materials

Title
Description
Actions
Title
Supporting Information for "Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines"
Description
Contains synthetic procedures, NMR data, and NMR spectra
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Now Published

Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines [opens in a new tab]
Cara R. Aversa-Fleener, Daniel K. Chang, Allegra L. Liberman-Martin journal article
Organometallics , Volume 40, Issue 24
Online publication date: Dec 16, 2021

Version History

Oct 20, 2021 Version 1

Metrics

824
397
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2021-zfvc9
D O I: 10.26434/chemrxiv-2021-zfvc9 [opens in a new tab]

Funding

American Chemical Society Petroleum Research Fund
62239-UNI1

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

Share