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Photocatalytic reduction of nicotinamide co-factor by perylene sensitized Rh(III) complexes

08 October 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report a catalytically active intramolecular photocatalyst, which combines a perylene photosensitizer and a Rh(III) catalyst. Spectroscopic studies reveal the formation of a charge-separated perylene radical cation-Rh(II) intermediate that results in a catalytically active species in the presence of protons.

Keywords

Ultrafast Spectroscopy
Photocatalysis
Perylene
Rhodium-catalyst

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Version History

Oct 08, 2021 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2021-g9bfz
D O I: 10.26434/chemrxiv-2021-g9bfz [opens in a new tab]

Funding

Deutsche Forschungsgemeinschaft
364549901
Verband der Chemischen Industrie
Kekulé Fellowship (J. B.)

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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