Errors in the Use of NMR to Test Molecular Mobility during a Chemical Reaction

Lucy Fillbrook; Jan-Philipp Günther; Günter Majer; William S. Price; Peer Fischer; Jonathon Beves

doi:10.26434/chemrxiv.14306771.v1

Physical Chemistry

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Errors in the Use of NMR to Test Molecular Mobility during a Chemical Reaction

29 March 2021, Version 1

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This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A study reported in The Journal of Physical Chemistry Letters (12 (2021) 2370) of “boosted mobility” measured by diffusion NMR experiments contains significant errors in data analysis and interpretation. We carefully reanalyzed the same data and find no evidence of boosted mobility, and we identify several sources of error.

Keywords

time-resolved diffusion

Nuclear magnetic resonance (NMR)

pulsed field gradient spin echo

pulsed field gradient stimulated echo

Supplementary materials

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Mar 29, 2021 Version 1

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The content is available under CC BY NC ND 4.0

DOI

10.26434/chemrxiv.14306771.v1

Author’s competing interest statement

No Conflict of Interest

Errors in the Use of NMR to Test Molecular Mobility during a Chemical Reaction

Authors

Abstract

Keywords

Supplementary materials

Comments

Version History

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DOI

Author’s competing interest statement

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