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Fixation of Dinitrogen at an Asymmetric Binuclear Titanium N2 Complex

16 March 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report the first example of a binuclear Ti–N2 complex with
triphenolamine that adopts trigonal bipyramidal and octahedral
geometries on the Ti centers. The activated N2 was reduced to
ammonia with 154% yield (per Ti atom) in the presence of
proton and electron sources.

Keywords

Nitrogen Fixation
Dinitrogen Activation
Ammonia
Triphenolamine
Titanium

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Version History

Mar 16, 2021 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.14213876.v1
D O I: 10.26434/chemrxiv.14213876.v1 [opens in a new tab]

Funding

Ministry of Education (South Korea) NRF-2020R1A6A3A01100585
Ministry of Education (South Korea) NRF-2019M1A2A2067940

Author’s competing interest statement

No Conflict of Interest

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