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Beyond Thin Films: Clarifying the Impact of c-Li15Si4 Formation in Thin Film, Nanoparticle, and Porous Si Electrodes

09 March 2021, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Analysis of the role of c-Li15Si4 in performance of silicon-based anodes in lithium ion batteries. This work indicates that concerns about the c-Li15Si4 phase in silicon nanoparticles and porous silicon electrodes should mainly focus on the stability of the SEI and a reduction of irreversible electrolyte reactions.

Keywords

Silicon
porous silicon
films
lithium-ion batteries
anodes
nanoparticles
Li15Si4
crystallization
solid electrolyte interphase

Supplementary materials

Title
Description
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Title
Crystallization in Silicon Nanoparticles SI 2021 03 06 PDF
Description
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Version History

Mar 09, 2021 Version 1

Version Notes

Version 1 before submission to ACS journal.

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.14175389.v1
D O I: 10.26434/chemrxiv.14175389.v1 [opens in a new tab]

Funding

Future Energy Systems (T12-P04)
NSERC (RGPIN-2018-04294)
Western Economic Diversification (000014328)
Canada Research Chairs (CRC 207142)

Author’s competing interest statement

None

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