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Green Synthesis: Novel method for Substituted Anilines from its Benzyl Azides

04 January 2021, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A unique and novel synthetic method was developed to generate substituted
anilines from its benzyl azides having ortho/para electron withdrawing group (EWG),
and when these groups are at meta position gives aldehyde, instead. This approach is
an inexpensive, simple, fast, efficient at room temperature. This protocol is easily
amenable to large scale preparation.

Keywords

substituted benzylazides
green chemistry
selectivity
electron withdrawing groups
substituted anilines.
extrusion of carbon.

Supplementary materials

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Azide experimental 12-31-2020 ready to submission
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Azide manuscript 12-31-2020 ready to submission,
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Version History

Jan 04, 2021 Version 2

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License

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BY
The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.12967535.v2
D O I: 10.26434/chemrxiv.12967535.v2 [opens in a new tab]

Funding

National Science Council of Taiwan, (ROC)

Author’s competing interest statement

There is no Competing Interests pending

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