Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

Planar Hexacoordinate Carbons: Half Covalent Half Ionic

01 December 2020, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The global minima of thirteen combinations of atoms with formula CE3M3+ (E=S-Te and M=Li-Cs) adopt a planar structure with carbon covalently bonded to three chalcogens and ionically bonded to the three alkali-metals to stabilize the first global minima structures containing planar hexacoordinate carbon atoms.

Keywords

hexacoordination
carbon hypercoordination
IQA

Supplementary materials

Title
Description
Actions
Title
Planar hexacoordinate carbon SI
Description
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Version History

Dec 01, 2020 Version 1

Metrics

3,029
617
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.13296674.v1
D O I: 10.26434/chemrxiv.13296674.v1 [opens in a new tab]

Funding

Fondecyt 1181165
SEP-Cinvestav.2018-57

Author’s competing interest statement

No conflict of interest

Share