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Solvent Induced Enantioselectivity Reversal in a Chiral Metal Organic Framework

27 October 2020, Version 1

Abstract

Solvent induced enantioselectivity reversal is a rarely reported phenomenon in porous homochiral materials. Similar behaviour has been studied in chiral HPLC, where minor mobile phase modifications can induce elution order reversal. We report the first instance of solvent-induced enantioselectivity reversal for homochiral MOF ZnBLD, highlighting the complex enantioselectivity behaviour

Content

Supplementary materials

Slater Hill Ladewig ChemRxiv SI

Supplementary weblinks

http://doi.org/10.5281/zenodo.4126252

Version History

Oct 27, 2020 Version 1

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CC logo BY logo NC logo ND logo
The content is available under CC BY NC ND 4.0 CreativeCommons.org [opens in a new tab]

DOI

10.26434/chemrxiv.13138997.v1
D O I: 10.26434/chemrxiv.13138997.v1 [opens in a new tab]

Author’s competing interest statement

No conflict of interest to declare.

Keywords

Metal organic framework
Adsorption
Enantioselective
Eantioselectivity reversal

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This content is an early or alternative research output and has not been peer-reviewed at the time of posting.