Step-Growth Polymerisation of Alkyl Acrylates via Concomitant Oxa-Michael and Transesterification Reactions

28 August 2020, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Herein we propose an auto-tandem catalytic approach towards the preparation of poly(ester-ether)s from simple alkyl acrylates and diols. By combining oxa-Michael addition with transesterification the preparation of hydroxy functionalised acrylate monomers can be avoided.

Keywords

Oxa-Michael addition
Transesterification
auto-tandem catalysis
poly(ester-ether)

Supplementary materials

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slugovc etal ESI auto-tandem chemrxiv
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