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Step-Growth Polymerisation of Alkyl Acrylates via Concomitant Oxa-Michael and Transesterification Reactions

28 August 2020, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Herein we propose an auto-tandem catalytic approach towards the preparation of poly(ester-ether)s from simple alkyl acrylates and diols. By combining oxa-Michael addition with transesterification the preparation of hydroxy functionalised acrylate monomers can be avoided.

Keywords

Oxa-Michael addition
Transesterification
auto-tandem catalysis
poly(ester-ether)

Supplementary materials

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slugovc etal ESI auto-tandem chemrxiv
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Now Published

Step-growth polymerisation of alkyl acrylates via concomitant oxa-Michael and transesterification reactions [opens in a new tab]
Karin Ratzenböck, David Pahovnik, Christian Slugovc journal article
Polymer Chemistry , Volume 11, Issue 47
Online publication date: 2020

Version History

Aug 28, 2020 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.12886961.v1
D O I: 10.26434/chemrxiv.12886961.v1 [opens in a new tab]

Funding

Christian Doppler Research Association (CDL-Organocatalysis in Polymerization)

Author’s competing interest statement

No conflict of interest

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