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Squeezing Bi: PNP and P2N3 Pincer Complexes of Bismuth(III

21 April 2020, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report the first application of a rigid P2N3 pincer ligand in p-block chemistry by preparing its bismuth complex. We also report the first example of bismuth complexes featuring a flexible PNP pincer ligand, which shows phase-dependent structural dynamics. Highly electrophilic, albeit thermally unstable, Bi(III) complexes of the PNP ligand were also prepared.

Keywords

bismuth
pincer
crystallography
redox
Lewis acid
cation

Supplementary materials

Title
Description
Actions
Title
PNPBiexprimental-ChemRxiv
Description
Actions

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Version History

Apr 21, 2020 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.12149502.v1
D O I: 10.26434/chemrxiv.12149502.v1 [opens in a new tab]

Author’s competing interest statement

None

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