Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

Electrocatalytic C–N Coupling via Anodically Generated Hypervalent Iodine Intermediates

30 December 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Development of new electrosynthetic chemistry promises to impact the efficiency and sustainability of organic synthesis. Here we demonstrate that anodically generated hypervalent iodine intermediates effectively couple interfacial electron transfer with oxidative C-H/N-H coupling chemistry.

Keywords

Hypervalent Iodine
Electrocatalysis Paradigm
C-H Functionalization

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Now Published

Electrocatalytic C–N Coupling via Anodically Generated Hypervalent Iodine Intermediates [opens in a new tab]
Asim Maity, Brandon L. Frey, Nathanael D. Hoskinson, David C. Powers journal article
Journal of the American Chemical Society , Volume 142, Issue 11
Online publication date: Mar 04, 2020

Version History

Dec 30, 2019 Version 1

Metrics

3,273
910
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.11472549.v1
D O I: 10.26434/chemrxiv.11472549.v1 [opens in a new tab]

Funding

Welch Foundation A-1907
National Science Foundation 1848135

Author’s competing interest statement

No conflict

Share