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Relay Cross Metathesis for the Ascent of the Terpenoids

13 June 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report the design and implementation of a relay cross metathesis (ReXM) reaction for the ascent of the terpenoids in an iterative protocol using naturally occurring terpenoid building blocks. The method is used for the synthesis of a diterpene-benzoate macrolide of biogenetic relevance to the bromophycolide family of natural products.

Keywords

Relay Cross Metathesis
Olefin metathesis
Natural Product
Terpene

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Relay Cross Metathesis for the Ascent of the Terpenoids ChemRxiv SI
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Version History

Jun 13, 2019 Version 1

Version Notes

ChemRxiv_v1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.8267837.v1
D O I: 10.26434/chemrxiv.8267837.v1 [opens in a new tab]

Funding

EP/P030742/1

Author’s competing interest statement

No conflict of interest.

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