Cr(II) and Cr(I) PCP Pincer Complexes: Synthesis, Structure, and  Catalytic Reactivity

Daniel Himmelbauer; Berthold Stöger; Luis F. Veiros; Marc Pignitter; Karl Kirchner

doi:10.26434/chemrxiv.10116692.v1

Inorganic Chemistry

Search within Inorganic Chemistry

Cr(II) and Cr(I) PCP Pincer Complexes: Synthesis, Structure, and Catalytic Reactivity

07 November 2019, Version 1

Working Paper

Show author details

This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report the synthesis of the square-planar Cr(II) PCP complex [Cr(POCOP-tBu)(Br)] which is a valuable precursor for novel chromium borohydride PCP pincer complexes in formal oxidation states +I and +II.

Keywords

Chromium

PCP pincer ligand

nitrosyl complexes

Supplementary materials

Title

Description

Actions

Title

all

Description

Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here .

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Now Published

Cr(II) and Cr(I) PCP Pincer Complexes: Synthesis, Structure, and Catalytic Reactivity

Daniel Himmelbauer, Berthold Stöger, Luis F. Veiros, Marc Pignitter, Karl Kirchner journal article

Organometallics , Volume 38, Issue 24

Online publication date: Dec 04, 2019

Version History

Nov 07, 2019 Version 1

Version Notes

Version 1.0

Metrics

3,047

519

Views

Downloads

Citations

License

The content is available under CC BY NC ND 4.0

DOI

10.26434/chemrxiv.10116692.v1

Funding

Austrian Science Fund P29584-N28

Author’s competing interest statement

There are is no conflict of interest