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Decarboxylative C–C and C–N Bond Formation via Ligand-Accelerated Iron Photocatalysis

13 September 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Through iron photocatalysis, a mild and effective protocol for the decarboxylative C–C and C–N bond formation has been achieved. The carboxylic acids readily underwent radical decarboxylation in the presence of Fe2(SO4)3 and di-(2-picolyl)amine with visible light irradiation. The resultant alkyl radicals then reacted with Michael acceptors or azodicarboxylates to furnish the adducts.

Keywords

Ligand-Accelerated
Iron Photocatalysis
Decarboxylative
C–C Bond Formation
C–N Bond Formation

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Version History

Sep 13, 2019 Version 1

Version Notes

The first version for Chemrxiv.

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.9816950.v1
D O I: 10.26434/chemrxiv.9816950.v1 [opens in a new tab]

Funding

Natural Science Foundation of Shanghai (19ZR1468700)

Author’s competing interest statement

The authors declare no competing financial interest.

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