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NMR-Enhanced Crystallography Aids Open Metal-Organic Framework Discovery Using Solvent-Free Accelerated Aging

17 June 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

NMR-enhanced crystallography enables the characterization of a novel cadmium-based, open metal-organic framework (MOF) from a solvent-free "accelerated aging" process. Whereas accelerated aging was devised as a clean, mild route for making MOFs, these results highlight how it application in materials discovery and characterization is aided by a combination of X-ray diffraction and solid-state NMR spectroscopy.

Keywords

NMR crystallography
metal-organic frameworks
solvent-free
structure determination
materials discovery
topology

Supplementary materials

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Now Published

NMR-Enhanced Crystallography Aids Open Metal–Organic Framework Discovery Using Solvent-Free Accelerated Aging [opens in a new tab]
Christopher A. O’Keefe, Cristina Mottillo, Jogirdas Vainauskas, László Fábián, Tomislav Friščić, Robert W. Schurko journal article
Chemistry of Materials , Volume 32, Issue 10
Online publication date: Apr 22, 2020

Version History

Jun 17, 2019 Version 1

Version Notes

This is version 1.

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.8281787.v1
D O I: 10.26434/chemrxiv.8281787.v1 [opens in a new tab]

Funding

NSERC Discovery Grant (RGPIN-2017-06467)
E. W. R. Steacie Memorial Fellowship (SMFSU 507347-17)

Author’s competing interest statement

We declare no conflict of interest.

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