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Access to Fe(II) Bis(σ-B-H) Aminoborane Complexes via Protonation of a Borohydride Complex and Dehydrogenation of Amine-Boranes

02 May 2019, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report on the first synthesis and structural characterization of the iron based aminoborane complexes. These species are formed upon protonation of a borohydride complex by ammonium salts.

Keywords

Iron Pincer Complexes
Aminoboranes
dehydrogenation

Supplementary materials

Title
Description
Actions
Title
Fe Aminoborane Complexes
Description
Actions
Title
Fe Aminoborane ESI
Description
Actions

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Version History

May 02, 2019 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.8063120.v1
D O I: 10.26434/chemrxiv.8063120.v1 [opens in a new tab]

Funding

Austrian Science Fund - P29584-N28

Author’s competing interest statement

no conflict of interest

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