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Reinventing Hydroacylation: A Redox-Neutral Synthesis of Ketones by Coupling of Alkenes and Amides

30 October 2018, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Herein, we present a new concept for the hydroacylation of alkenes employing amides in a metal-free regime, proceeding by an entirely new mechanism and offering orthogonal reactivity to the conventional, metal-catalysed alternatives.

Keywords

alkenes
hydroacylation
amides
metal-free
redox-neutral

Supplementary materials

Title
Description
Actions
Title
Hydroacylation SI
Description
Actions

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Version History

Oct 30, 2018 Version 1

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License

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.7265519.v1
D O I: 10.26434/chemrxiv.7265519.v1 [opens in a new tab]

Funding

FWF P30226, ERC CoG VINCAT

Author’s competing interest statement

No conflict of interest

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