Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

Kent O. Kirlikovali; Jonathan C. Axtell; Kierstyn Anderson; Peter I. Djurovich; Arnold L. Rheingold; Alexander Spokoyny

doi:10.26434/chemrxiv.6670739.v1

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Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

26 June 2018, Version 1

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Abstract

We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(o-carborane) (bc). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

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vertex differentiation

boron cluster

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Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

Kent O. Kirlikovali, Jonathan C. Axtell, Kierstyn Anderson, Peter I. Djurovich, Arnold L. Rheingold, Alexander M. Spokoyny journal article

Organometallics , Volume 37, Issue 18

Online publication date: Sep 04, 2018

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Jun 26, 2018 Version 1

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The content is available under CC BY NC ND 4.0

DOI

10.26434/chemrxiv.6670739.v1

Author’s competing interest statement

No conflicts of interest are associated with this submission.

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

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Abstract

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Supplementary materials

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Author’s competing interest statement

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