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Abstract
By developing a
Pd(0)/Mandyphos catalyst, we have achieved a three-component aminoarylation of
alkynes to generate enamines, which upon hydrolysis yield either α-arylphenones or α,α-diarylketones. This
Pd-catalyzed method overcomes well-established pathways to enable the use of
amines as traceless directing groups for C–C bond formation.
Supplementary materials
Title
SI ChemRxiv Dong
Description
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